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The Colorado Plateau, USA, is bordered by Pleistocene continental rift volcanism in New Mexico, Arizona, and Utah. While most of the eruptions have been basaltic, rhyolitic domes, tuffs, and lavas have been produced. On the western margin, where the Colorado Plateau meets the Basin and Range extensional province, the Black Rock Desert of central Utah hosts Pleistocene-Holocene bimodal basalt-rhyolite volcanic activity. The South Twin Complex consists of six rhyolites within a single basin erupted between 2.45 and 2.40 Ma, and they precede all Pleistocene basalts of the region. In this work, we share a new rhyolite eruptive stratigraphy based on high precision 40Ar/39Ar dates and examine the zircon crystal cargo from each eruptive center. The new eruption ages allow us to examine the spatial and temporal distribution of volcanism in the South Twin Complex, whereas the zircon crystal morphology, geochemistry, and U/Pb dating allow us to assess the conditions and timescales of silicic magma processes in the subvolcanic plumbing system. Our data suggest the plumbing system beneath the region experienced punctuated influxes of magma over a brief period of thousands to tens of thousands of years. Further, the timescales and patterns of silicic magma assembly and evolution of this small anorogenic region are similar to those observed within the voluminous Yellowstone province, suggesting that the volume of magmatic flux does not control magmatic evolution in intercontinental settings. 

The origins and evolution of small-volume, high-silica intercontinental rhyolites have been attributed to numerous processes such as derivation from granitic partial melts or small melt fractions remaining from fractional crystallization. Investigations into the thermo-chemical-temporal evolution of these rhyolites has provided insights into the storage and differentiation mechanisms of small volume magmas. In the Mineral Mountains, Utah, high-silica rhyolites erupted through Miocene granitoids between ca. 0.8 and 0.5 Ma, and produced numerous domes, obsidian flows, and pyroclastic deposits. Temporally equivalent basalts erupted in the valleys north and east of the Mineral Mountains, hinting at a potential relationship between mafic and felsic volcanic activity. Here we test competing hypotheses. Are the rhyolites products of extreme fractionation of the coeval basalts? Or do they represent anatectic melts of the granitoids through which they erupted? We address these questions through modeling with new whole rock geochemical data and zircon trace element chemistry, thermometry, and U/Pb LA-ICPMS dates. We couple these data with new 40Ar/39Ar eruption ages to improve upon the volcanic stratigraphy and address the recurrence interval for the most evolved rhyolites. Geochemical data from zircon crystals extracted from six domes suggest increasing differentiation with age and eruptive location, however there is minimal evidence for recycling of earlier crystallized zircon. These data suggest that magma batches were isolated from one another and zircon nucleation and crystallization occurred close to the eruption, thus limiting the residence time of the magmas. These data also perhaps suggest that the magmas were generated in small batches within each of the granitoids rather than from a large crystal mush body underlying the region, as seen at large silicic systems. Our preliminary geochemical models and zircon petrochronology eliminate extreme fractionation and favor local anatectic melting of different granitoids as a mechanism to produce chemical signatures observed in the Quaternary rhyolites in the Mineral Mountains. 

Formation and evolution of the basal layer in large landslides has important implications for processes that reduce frictional resistance to sliding. In this report, we show that zircon geochronology and tectonic provenance can be used to investigate the basal layer of the gigantic-scale Markagunt gravity slide of Utah, USA. Basal layer and clastic injectite samples have unique tectonic chronofacies that identify the rock units that were broken down during emplacement. Our results show that basal material from sites on the former land surface is statistically indistinguishable and formed primarily by the breakdown of upper plate lithologies during sliding. Decapitated injectites have a different tectonic chronofacies than the local basal layer, with more abundant lower plate-derived zircons. This suggests clastic dikes formed earlier in the translation history from a structurally deeper portion of the slide surface and a compositionally different basal layer before being translated to their current position. 

The physical processes that facilitate long‐distance translation of large‐volume gravity slides remain poorly understood. To better understand these processes and the controls on runout distance, we conducted an outcrop and microstructural characterization of the Sevier gravity slide across the former land surface and summarize findings of four key sites. The Sevier gravity slide is the oldest of three mega‐scale (>1,000 km²) collapse events of the Marysvale volcanic field (Utah, USA). Field observations of intense deformation, clastic dikes, pseudotachylyte, and consistency of kinematic indicators support the interpretation of rapid emplacement during a single event. Furthermore, clastic dikes and characteristics of the slip zone suggest emplacement involved mobilization and pressurized injection of basal material. Across the runout distance, we observe evidence for progressive slip delocalization along the slide base. This manifests as centimeter‐ to decimeter‐thick cataclastic basal zones and abundant clastic dikes in the north and tens of meters thick basal zones characterized by widespread deformation of both slide blocks and underlying rock near the southern distal end of the gravity slide. Superimposed on this transition are variations in basal zone characteristics and slide geometry arising from interactions between slide blocks during dynamic wear and deposition processes and pre‐existing topography of the former land surface. These observations are synthesized into a conceptual model in which the presence of highly pressurized fluids reduced the frictional resistance to sliding during the emplacement of the Sevier gravity slide, and basal zone evolution controlled the effectiveness of dynamic weakening mechanisms across the former land surface.

 

The production of hydrogen fuels, via water splitting, is of practical relevance for meeting global energy needs and mitigating the environmental consequences of fossil-fuel-based transportation. Water photoelectrolysis has been proposed as a viable approach for generating hydrogen, provided that stable and inexpensive photocatalysts with conversion efficiencies over 10% can be discovered, synthesized at scale, and successfully deployed (Pinaud et al. , Energy Environ. Sci. , 2013, 6 , 1983). While a number of first-principles studies have focused on the data-driven discovery of photocatalysts, in the absence of systematic experimental validation, the success rate of these predictions may be limited. We address this problem by developing a screening procedure with co-validation between experiment and theory to expedite the synthesis, characterization, and testing of the computationally predicted, most desirable materials. Starting with 70 150 compounds in the Materials Project database, the proposed protocol yielded 71 candidate photocatalysts, 11 of which were synthesized as single-phase materials. Experiments confirmed hydrogen generation and favorable band alignment for 6 of the 11 compounds, with the most promising ones belonging to the families of alkali and alkaline-earth indates and orthoplumbates. This study shows the accuracy of a nonempirical, Hubbard-corrected density-functional theory method to predict band gaps and band offsets at a fraction of the computational cost of hybrid functionals, and outlines an effective strategy to identify photocatalysts for solar hydrogen generation. 

Abstract The 40Ar/39Ar dating method is among the most versatile of geochronometers, having the potential to date a broad variety of K-bearing materials spanning from the time of Earth’s formation into the historical realm. Measurements using modern noble-gas mass spectrometers are now producing 40Ar/39Ar dates with analytical uncertainties of ∼0.1%, thereby providing precise time constraints for a wide range of geologic and extraterrestrial processes. Analyses of increasingly smaller subsamples have revealed age dispersion in many materials, including some minerals used as neutron fluence monitors. Accordingly, interpretive strategies are evolving to address observed dispersion in dates from a single sample. Moreover, inferring a geologically meaningful “age” from a measured “date” or set of dates is dependent on the geological problem being addressed and the salient assumptions associated with each set of data. We highlight requirements for collateral information that will better constrain the interpretation of 40Ar/39Ar data sets, including those associated with single-crystal fusion analyses, incremental heating experiments, and in situ analyses of microsampled domains. To ensure the utility and viability of published results, we emphasize previous recommendations for reporting 40Ar/39Ar data and the related essential metadata, with the amendment that data conform to evolving standards of being findable, accessible, interoperable, and reusable (FAIR) by both humans and computers. Our examples provide guidance for the presentation and interpretation of 40Ar/39Ar dates to maximize their interdisciplinary usage, reproducibility, and longevity. 

The citizen Continental-America Telescopic Eclipse (CATE) Experiment was a new type of citizen science experiment designed to capture a time sequence of white-light coronal observations during totality from 17:16 to 18:48 UT on 2017 August 21. Using identical instruments the CATE group imaged the inner corona from 1 to 2.1 RSun with 1.″43 pixels at a cadence of 2.1 s. A slow coronal mass ejection (CME) started on the SW limb of the Sun before the total eclipse began. An analysis of CATE data from 17:22 to 17:39 UT maps the spatial distribution of coronal flow velocities from about 1.2 to 2.1 RSun, and shows the CME material accelerates from about 0 to 200 km s⁻¹across this part of the corona. This CME is observed by LASCO C2 at 3.1–13 RSun with a constant speed of 254 km s⁻¹. The CATE and LASCO observations are not fit by either constant acceleration nor spatially uniform velocity change, and so the CME acceleration mechanism must produce variable acceleration in this region of the corona.